Gas phase reaction of OH radicals with (E)-β-farnesene at 296 ± 2 K: Rate coefficient and carbonyl products
✍ Scribed by Ivan Kourtchev; Iustinian Bejan; John R. Sodeau; John C. Wenger
- Book ID
- 113480869
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 448 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1352-2310
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## Abstract The relative‐rate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2‐methyl‐3‐buten‐2‐ol (__k__~1~), 3‐methyl‐3‐buten‐1‐ol (__k__~2~), and 3‐methyl‐2‐buten‐1‐ol (__k__~3~), in the gas phase. OH radicals were prod
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo
Using a relative rate method, rate constants have been determined at 296 5 2 K for the gas-phase reactions of the OH radical with toluene, the xylenes, and the trimethylbenzenes. Using the recommended literature rate constant for the reaction of OH radicals with propene of (2.66 2 0.40) x lo-" cm3 m
Relative rate constants for the reaction of OH radicals with a seqies of cY,P-unsaturated carbonyls have been determined at 299 & 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with propene of 2.52 X 10-l' cm3/molec.s, th