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Reaction of energetic hydrogen atoms with 1-chloropropane

✍ Scribed by P. L. Gould; G. A. Oldershaw

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 304 KB
Volume: 25
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550250804

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✦ Synopsis

The reaction of photochemically generated energetic hydrogen atoms with 1-chloropropane, reaction ( l ) ,

(1)

has been examined for translational energies of H' in the range 40 to 110 kJ mol-'. Integral probabilities for reaction (1) have been determined, and the phenomenological threshold energy is 47 2 10 kJ mol-'. The moderating effect of C02 on reaction (1) for hydrogen atoms of initial energy 108 kJ mol-' has also been studied.

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