## Abstract Energetic hydrogen atoms generated by photolysis of HBr or HI react with CDCl~3~ by abstracting either a deuterium atom (1) or a chlorine atom (2): equation image The integral probability of reaction (2) has been measured for several defined initial translational energies of H^\*^, an
Reaction of hot H atoms with CD3Br
β Scribed by Geoffrey A. Oldershaw; Alan Smith
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 312 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
Energetic H atoms produced by photolysis of gaseous HI react with CD,Br by D abstraction (1) and Br abstraction (2) and possibly also by the substitution reactions (4) and (5).
π SIMILAR VOLUMES
Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for
## Abstract Effects of deuterium substitution in propylene on the relative rates of H(D) atom abstraction from and addition to the olefin, and on the orientation of H(D) atom addition, have been studied in the gas phase at room temperature. Effects of isotopic substitution of the olefinic hydrogen