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Reaction of Cyanomethylene with Nitric Oxide and Oxygen at 298 K: HCCN + NO, O 2

✍ Scribed by Adamson, J. D.; DeSain, J. D.; Curl, R. F.; Glass, G. P.

Book ID: 126154363
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 166 KB
Volume: 101
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp962686g

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Rcccivcd 30 Apnl 1982 SO:, photodissociation at 193 nm (AIF cxclmer lmr) ha been used to create SO radicals; the chcmdumincsccncc from the SO + 03 reaction has been used to follow the SO ndical decay. Rate coefticicnls at 298 K of (1 07 t 0.16) x 10-r6, (1 06 f 0 16) x 10-r3, and (1 48 k 0 20) x IO-

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CS radicals have been produced by photodissociation of CS2 at 193 MI and their disappearance monitored by LIF\_ The vibrationally excited CS radicals rapidly relax to CS(v = 0). At 298 K, the rate coeffkients for CS(u = 0) reactions with 02, 03 and NO\* are (2.9 +\_ 0.4) x lo-", (3.0 + 0.4) X lo-I6

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## Abstract Azulene, which is isomeric with naphthalene, was studied to determine whether it behaves like a polycyclic aromatic hydrocarbon or an alkene in its gas‐phase reactions with OH and NO~3~ radicals and O~3~. Using relative rate methods, rate constants for the reactions of azulene with OH a

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The kinetics of CzH50 and CzH502 radicals with NO have been studied at 298 K using the discharge flow technique coupled to laser induced fluorescence (LIF) and mass spectrometry analysis. The temporal profiles of CzH5O were monitored by LIF. The rate constant for CzH5O + NO -Products (21, measured i

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