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Reaction of CH3O2+HO2 in air at 295 K: A product study

✍ Scribed by Timothy J. Wallington; Steven M. Japar

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 562 KB
Volume: 167
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)85461-k

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✦ Synopsis

Fourier transform infrared spectroscopy was used to identify and quantify methylhydroperoxide as the dominant product of the gas phase reaction of methylperoxy radicals with hydroperoxy radicals. At 295 K, and 700 Torr total pressure of air, 92 f 8% of the reaction of CH102 with HO2 proceeds via CHa02 + HO*-+ CH,OOH + Oz. Results are discussed with respect to the previous kinetic and mechanistic studies of peroxy radicals and computer models of atmospheric chemistry.

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