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FTIR product study of the reaction of C2H5O2+HO2 in air at 295 K

โœ Scribed by Timothy J. Wallington; Steven M. Japar


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
400 KB
Volume
166
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES


Reaction of CH3O2+HO2 in air at 295 K: A
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Fourier transform infrared spectroscopy was used to identify and quantify methylhydroperoxide as the dominant product of the gas phase reaction of methylperoxy radicals with hydroperoxy radicals. At 295 K, and 700 Torr total pressure of air, 92 f 8% of the reaction of CH102 with HO2 proceeds via CHa

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Fourier transform infrared spectroscopy was used to identify and quantify products of the self-reaction of chloroethylperoxy radicals, CH2C1CH20z, formed in the photolysis of Cl&H4 mixtures in 700 Torr total pressure of synthetic air at 295 K. From these measurements, branching ratios for the reacti

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Using Fourier transform infrared spectroscopy, the ethene yield from the reaction of C2H5 radicals with O2 has been determined to be 1.50 ? 0.098, 0.85 ? 0.118, and < O . l % at total pressures of 25, 50, and 700 torr, respectively. Additionally, the rate constant of the reaction of CzHs radicals wi

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The reaction between CzH5 and 0 2 a t 295 K has been studied with a flow reactor sampled by a mass spectrometer. With helium as the carrier gas the rate coefficient was found to increase from (1.2 f 0.3) X cm3/s as [He] was increased from 2 X 10I6 to 3.4 X 1017 The importance of to (3.6 f 0.9) has

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Fourier transform infrared spectroscopy was used to identify and quantify products of the self reaction of ethylperoxy radicals, C2H502, formed in the photolysis of C12/C2H6 mixtures in 700 torr total pressure of synthetic air a t 295 K . From these measurements, branching ratios for the reaction ch

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Fourier transform infrared spectroscopy was used to establish methyl-d, hydroperoxide as the dominant product of the gas phase reaction of CD,02 radicals with HO\* radicals. Over the total pressure range I O-700 Torr, 100 + 4% of the reaction of CD302 with HO2 proceeds via the channel CD302+HOz+CDX