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Reaction of CF 3 Radicals with CO and O 2 . Isolation of Bis(trifluoromethyl)peroxydicarbonate, CF 3 OC(O)OOC(O)OCF 3 , and Identification of Bis(trifluoromethyl)trioxydicarbonate, CF 3 OC(O)OOOC(O)OCF 3

✍ Scribed by Argüello, G. A.; Willner, H.; Malanca, F. E.

Book ID
120199812
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
58 KB
Volume
39
Category
Article
ISSN
0020-1669

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Earlier arguments concerning D(CF302-CF3) and D(CF3-02) are shown to be probably wrong. New values of 86 and 49 kcal/mol, respectively, are derived. C-0 bond strengths are compared between CF3-and CH3-containing compounds. This relation is of value only if D,(Oz) is independent of X. This is equival