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Synthesis and Characterization of Trifluoromethyl Fluoroformyl Peroxycarbonate, CF 3 OC(O)OOC(O)F

✍ Scribed by Burgos Paci, Maximiliano A.; García, Plácido; Malanca, Fabio E.; Argüello, Gustavo A.; Willner, Helge

Book ID
126187031
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
72 KB
Volume
42
Category
Article
ISSN
0020-1669

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Kinetics of the thermal decomposition of
Kinetics of the thermal decomposition of bis(trifluoromethyl) peroxydicarbonate, CF3OC(O)OOC(O)OCF3
✍ Maximiliano A. Burgos Paci; Gustavo A. Argüello; Plácido García; Helge Willner 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB

## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca