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Stucture and Conformational Properties of Bis(trifluoromethyl) Peroxydicarbonate, CF 3 OC(O)O−OC(O)OCF 3

✍ Scribed by Hnyk, Drahomír; Macháček, Jan; Argüello, Gustavo A.; Willner, Helge; Oberhammer, Heinz


Book ID
118005774
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
83 KB
Volume
107
Category
Article
ISSN
1089-5639

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Kinetics of the thermal decomposition of
✍ Maximiliano A. Burgos Paci; Gustavo A. Argüello; Plácido García; Helge Willner 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB

## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca