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Reaction kinetics of O + ClO → Cl + O 2 between 252–347 K

✍ Scribed by Schwab, James J.; Toohey, D. W.; Brune, W. H.; Anderson, J. G.


Book ID
119720490
Publisher
American Geophysical Union
Year
1984
Tongue
English
Weight
562 KB
Volume
89
Category
Article
ISSN
0148-0227

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The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i

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Laser flash photolysis of C1,/Oz mixtures has been employed in conjunction with Cl( 2P,,2) detection by time-resolved resonance fluorescence spectroscopy to investigate equilibration kinetics for the reactions C1+Oz +O,:ClOO+O, at temperatures of I8 I-200 K and O2 pressures of 15-40 Torr. The third-