Kinetics of the reaction of CH 3 O 2 with ClO at 293 K
โ Scribed by Kenner, R. D.; Ryan, K. R.; Plumb, I. C.
- Book ID
- 119689110
- Publisher
- American Geophysical Union
- Year
- 1993
- Tongue
- English
- Weight
- 353 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1944-8007
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๐ SIMILAR VOLUMES
The reactions of CH3 radicals with O(3P) and 0 2 have been studied at 295 K in a gas flow reactor sampled by a mass spectrometer. For the reaction between CH3 and 0, conditions were such that [O] >> [CH3] and the methyl radicals decayed under pseudo-first-order conditions giving a rate coefficient o
The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i
## Abstract Kinetics for the reactions of OBrO with NO, O~3~, OClO, and ClO at 240โ350 K were investigated using the technique of discharge flow coupled with mass spectrometry. The Arrhenius expression for the OBrO reaction with NO was determined to be __k__~1~ = (2.37 ยฑ 0.96) ร 10^โ13^ exp[(607 ยฑ