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Kinetics and thermochemistry of the equilibria CH2Cl+O2⇔CH2ClO2 and CHCl2+O2⇔CHCl2O2

✍ Scribed by J.J. Russell; J.A. Seetula; D. Gutman; C.F. Melius; S.M. Senkan

Book ID
108392593
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
521 KB
Volume
23
Category
Article
ISSN
1540-7489

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📜 SIMILAR VOLUMES

A study of the self reaction of CH2ClO2
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A low-pressure discharge-flow system equipped with laser-induced fluorescence (LIF) detection of NO 2 and resonance-fluorescence detection of OH has been employed to study the self reactions CH 2 ClO 2 ϩ CH 2 ClO 2 : products (1) and CHCl 2 O 2 ϩ CHCl 2 O 2 : products (2), at T ϭ 298 K and P ϭ 1-3 T

GEm,HEm, andVEmat the temperature 298.15
GEm,HEm, andVEmat the temperature 298.15 K of {x(trans-CHCl:CHCl) + (1 −x) (CH2ClCH2Cl or CCl2:CCl2or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1 −x) (CCl2:CCl2or CHCl2CHCl2)}, and {xCCl2:CCl2+ (1 −x) CHCl2CHCl2}
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Excess molar enthalpies, excess molar volumes, and vapour pressures of {x(trans-CHCl:CHCl) + (1-x)(CH2ClCH2Cl or CCl2:CCl2 or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1-x)(CCl2:CCl2 or CHCl2CHCl2)}, and {xCCl2:CCl2 + (1-x)CHCl2CHCl2} were measured at the temperature 298.15 K. Activity coefficients and excess m