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GEm,HEm, andVEmat the temperature 298.15 K of {x(trans-CHCl:CHCl) + (1 −x) (CH2ClCH2Cl or CCl2:CCl2or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1 −x) (CCl2:CCl2or CHCl2CHCl2)}, and {xCCl2:CCl2+ (1 −x) CHCl2CHCl2}

✍ Scribed by I. Putze; R. Garriga; P. Pérez; M. Gracia

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
325 KB
Volume
27
Category
Article
ISSN
0021-9614

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✦ Synopsis

Excess molar enthalpies, excess molar volumes, and vapour pressures of {x(trans-CHCl:CHCl) + (1-x)(CH2ClCH2Cl or CCl2:CCl2 or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1-x)(CCl2:CCl2 or CHCl2CHCl2)}, and {xCCl2:CCl2 + (1-x)CHCl2CHCl2} were measured at the temperature 298.15 K. Activity coefficients and excess molar Gibbs free energies were fitted to a polynomial by Barker's method. For {xCH2ClCH2Cl+(1-x)CHCl2CHCl2} all excess functions are negative and we believe that a 1-1 complex is formed as in the solid state.

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