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The anions of CHCl3 and CH2Cl2

✍ Scribed by Y. Katsumura; R.E. Bühler


Book ID
108046119
Publisher
Elsevier Science
Year
1989
Weight
262 KB
Volume
34
Category
Article
ISSN
1359-0197

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Deactivation of I(2P1/2) by CH3Cl, CH2Cl
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Collisional deactivation of by the title compounds was investigated through 2 I( P ) 1/2 the use of the time-resolved atomic absorption of excited iodine atoms at Rate 206.2 nm. constants for atomic spin-orbit relaxation by CH 3 Cl, CH 2 Cl 2 , CHCl 3 , CCl 3 F, and CCl 4 are and Ϫ13 Ϫ13 Ϫ14 Ϫ15 3.

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Excess molar enthalpies, excess molar volumes, and vapour pressures of {x(trans-CHCl:CHCl) + (1-x)(CH2ClCH2Cl or CCl2:CCl2 or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1-x)(CCl2:CCl2 or CHCl2CHCl2)}, and {xCCl2:CCl2 + (1-x)CHCl2CHCl2} were measured at the temperature 298.15 K. Activity coefficients and excess m