Reaction between azide ion and [Ru(bipy)2(NO)Cl]2+
β Scribed by Meyer, Thomas J.; Miller, Frank J.
- Book ID
- 118063808
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 144 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
It is shown that at illumina ta! n-MO& and n-WScz electrodes the charge transfer of a hole from the crystal valence baud to certain redox ions in solution is cataiyzed by a [Ru(bipy),CI poly(4+inylpyridine)]Cl covering layer attached at the crystal surface. The coating behaves like a solid redox sys
It is found that charge-transfer of NO, with Cl, is tst at thermal energy. The Cl, ion reacts with NO, to produce Cl-and NOzCI, and SH-charge-transfers rapidly with both Cl, and NOz. From the exothermicitics implied it is deduced that EA (SH)< HA (NOz) < EA (Clz) or EX (Not) = 2.38 + 0.06 eV and EA