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Rates in the solvolysis of 2-octyl methanesulfonate in 30% aqueous dioxane in the presence of sodium azide and the question of borderline behavior

โœ Scribed by George A. Gregoriou


Book ID
118549907
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
347 KB
Volume
17
Category
Article
ISSN
0040-4039

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โœ George A. Gregoriou ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 343 KB

We have recently questioned 132 the evidence of Sneen and Larsen's study of the 2-octyl system3 in support of the particular unification of solvolysis mechanisms proposed by Sneen, 334 and originally the alleged observation of a between zero and first order rate dependence on the nucleophile. Such a