We have recently questioned 132 the evidence of Sneen and Larsen's study of the 2-octyl system3 in support of the particular unification of solvolysis mechanisms proposed by Sneen, 334 and originally the alleged observation of a between zero and first order rate dependence on the nucleophile. Such a
Salt effects in solvolysis. I. Some salt effects in the solvolysis of 2-octyl methanesulfonate in 30% aqueous dioxane
β Scribed by Photis J. Dais; George A. Gregoriou
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 325 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs
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