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Rate and product analytical study of the solvolysis of 3-chlorobenzyl arenesulfonates in aqueous 2,2,2-trifluoroethanol

✍ Scribed by Gordon, Isobel M.; Maskill, H.

Book ID: 111886676
Publisher: Royal Society of Chemistry
Year: 1991
Tongue: English
Weight: 358 KB
Volume: 12
Category: Article
ISSN: 1472-779X
DOI: 10.1039/p29910001951

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## Abstract The rate constants (log __k__) for the solvolysis of 4^e^‐substituted 2^e^‐ and 2^a^‐adamantyl __p__‐nitrobenzenesulfonates **14** and **15**, respectively, in 80% EtOH correlate linearly with the respective inductive substituent constants σ. Therefore, relative rates are controlled by