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Studies of Configuration. VII. the Solvolysis of 3- and 4-Methoxycyclohexyl Arenesulfonates 1,2

✍ Scribed by Noyce, Donald S.; Thomas, Barbara R.; Bastian, Bruce N.

Book ID
127243731
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
790 KB
Volume
82
Category
Article
ISSN
0002-7863

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## Abstract The rate constants (log __k__) for the solvolysis of 4^e^‐substituted 2^e^‐ and 2^a^‐adamantyl __p__‐nitrobenzenesulfonates **14** and **15**, respectively, in 80% EtOH correlate linearly with the respective inductive substituent constants Οƒ. Therefore, relative rates are controlled by