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Evidence for Dual and Distinct Mechanisms in the Solvolysis of 2-Octyl Brosylate in Aqueous Dioxane

โœ Scribed by Weiner, Henry.; Sneen, Richard A.


Book ID
126416936
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
147 KB
Volume
84
Category
Article
ISSN
0002-7863

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We have recently questioned 132 the evidence of Sneen and Larsen's study of the 2-octyl system3 in support of the particular unification of solvolysis mechanisms proposed by Sneen, 334 and originally the alleged observation of a between zero and first order rate dependence on the nucleophile. Such a