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Dissection of isotope effects. III Dissected α-deuterium effects in the solvolysis of 2-octyl brosylate in 65% aqueous ethanol

✍ Scribed by George A. Gregoriou; Fannie S. Varveri


Book ID
108384471
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
344 KB
Volume
19
Category
Article
ISSN
0040-4039

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A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue