Rate of reaction of OH radicals with cyanogen
โ Scribed by L.F. Phillips
- Book ID
- 107741106
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 201 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0010-2180
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๐ SIMILAR VOLUMES
The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T
The title reaction was studied by the direct time-resolved laser-induced lluorescence method at room temperature. The rate constants for the forward and reverse reactions were measured to be (1.92 0.5) x lo-" cm3 molecule-' s-l and (7.4&2.5)x IO4 s-', respectively. The rate constant forthe reaction
dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac
Absolute rate constants for the reaction OH + SO2 + N2 have been determined in the gas phase, at 297 K, in the pressure range SO-760 Torr. OH radicals were grnerated by flash photolysis of NzO/Hz mixtures and were monitored by time-resolved resonance absorption. The second-order rate constant $I was