The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T
Rate Constant for the Reaction of OH Radicals with Dichloromethane
β Scribed by Villenave, Eric; Orkin, Vladimir L.; Huie, Robert E.; Kurylo, Michael J.
- Book ID
- 127230676
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 116 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac
By using a relative rate technique, the rate constant for the gas phase reaction of OH radicals with diacetylene, a reaction considered to be of importance in fuel-rich acetylene oxidation, has been determined at 297 :t: 2K and atmospheric pressure. On the basis of a rate constant for the reaction o
Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o