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Rate constant for the reaction of OH radicals with diacetylene at 297 ± 2K

✍ Scribed by Roger Atkinson; Sara M. Aschmann

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
294 KB
Volume
58
Category
Article
ISSN
0010-2180

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✦ Synopsis

By using a relative rate technique, the rate constant for the gas phase reaction of OH radicals with diacetylene, a reaction considered to be of importance in fuel-rich acetylene oxidation, has been determined at 297 :t: 2K and atmospheric pressure. On the basis of a rate constant for the reaction of OH radicals with n-butane of 2.58 X 10-12 cm 3 molecule-~ s-1, a rate constant for the reaction of OH radicals with diacetylene of (1.62 + 0.06) × 10-II cm 3 molecule-~ s-m was obtained, where the error limit does not take into account the uncertainties in the rate constant for the reaction of OH radicals with n-butane.

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