## Abstract The relative‐rate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2‐methyl‐3‐buten‐2‐ol (__k__~1~), 3‐methyl‐3‐buten‐1‐ol (__k__~2~), and 3‐methyl‐2‐buten‐1‐ol (__k__~3~), in the gas phase. OH radicals were prod
Rate constant for the reaction of OH radicals with isopropylcyclopropane at 298 ± 2 K: Effects of ring strain on substituted cycloalkanes
✍ Scribed by Roger Atkinson; Sara M. Aschmann
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 176 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0538-8066
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Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with 1-and 2-propyl nitrate, 1-and 2-butyl nitrate and l-nitrobutane have been determined in the presence of one atmosphere of air at 298 t 2 K. Using rate constants for the reactions of the OH radical with pr
## Abstract Relative rate constants for the reaction of OH radicals with a series of ketones have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of hydroxyl radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−12^ cm^3^ mol
## Abstract Using methyl nitrite photolysis in air as a source of hydroxyl radicals, relative rate constants for the reaction of OH radicals with a series of alkanes and alkenes have been determined at 299 ± 2 K. The rate constant ratios obtained are: relative to __n__‐hexane = 1.00, neopentane 0.1
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo
Using a relative rate method, rate constants have been determined at 296 5 2 K for the gas-phase reactions of the OH radical with toluene, the xylenes, and the trimethylbenzenes. Using the recommended literature rate constant for the reaction of OH radicals with propene of (2.66 2 0.40) x lo-" cm3 m