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Rate constants for the reactions of the OH radical with the propyl and butyl nitrates and 1-nitrobutane at 298 ± 2 k

✍ Scribed by Roger Atkinson; Sara M. Aschmann

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
350 KB
Volume
21
Category
Article
ISSN
0538-8066

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✦ Synopsis

Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with 1-and 2-propyl nitrate, 1-and 2-butyl nitrate and l-nitrobutane have been determined in the presence of one atmosphere of air at 298 t 2 K. Using rate constants for the reactions of the OH radical with propane and cyclohexane of 1.15 x lo-'' and 7.49 x lo-'* cm3 molecule-' s-I, respectively, following rate constants (in units of lo-'' cm3 molecule-' s-' ) were obtained: l-propyl nitrate, 0.62; 2-propyl nitrate, 0.41; l-butyl nitrate, 1.78; 2-butyl nitrate, 0.93; and l-nitrobutane, 1.35. These rate constants are compared and discussed with the literature data.

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