The kinetics and mechanism of the reaction of BrO with dimethylsulfide [ DMS) have been studied by the mass spectrometric discharge-flow method in the temperature range (233-320) K and at a total pressure around 1 torr. The temperature dependence of the reaction rate constant k , = [ 1.5 ? 0 4 ) X 1
Rate of reaction of IO radicals with dimethylsulfide
โ Scribed by Daykin, E. P.; Wine, P. H.
- Book ID
- 119721501
- Publisher
- American Geophysical Union
- Year
- 1990
- Tongue
- English
- Weight
- 617 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0148-0227
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๐ SIMILAR VOLUMES
The kinetics of the reactions of 10, BrO, and C10 with DMS have been investigated at 298 K and total pressures of 0.5-6.8 mbar He using the discharge flow-mass spectrometry technique to monitor the halogen oxide radicals. Rate coefficients of (8.8 (2.7 f 0.5) x cm3 molecule-' 8-l have been obtained
The molecular-modulation-UV/visibleabsorption+ectroscopy technique has been used to investigate the simultaneous time. resolved behaviour of10 and HO2 produced by the pbotolysis of O3 in the presence of CH30H, Iz, O2 and Ar. This has enabled a direct measurement of the rate coefficient for the react