## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^
Rate constants of reactions of κ-carrageenan with hydrated electron and hydroxyl radical
✍ Scribed by L.V. Abad; S. Saiki; H. Kudo; Y. Muroya; Y. Katsumura; A.M. de la Rosa
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 496 KB
- Volume
- 265
- Category
- Article
- ISSN
- 0168-583X
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✦ Synopsis
The rate constants for the reactions of j-carrageenan with hydrated electron and hydroxyl radical was investigated by pulse radiolysis and laser photolysis. The kinetics of the reaction of hydrated electron indicates no seeming reaction with j-carrageenan. On the other hand, hydroxyl radical reacts very rapidly with j-carrageenan at a rate constant of approximately 1.2 • 10 9 M À1 s À1 . This rate constant varies with pH.
📜 SIMILAR VOLUMES
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21
The relative rate technique has been used to measure the rate coefficient for the reaction of the hydroxyl radical (OH) with methyl isobutyrate (MIB, (CH 3 ) 2 CHC(ϭO)-O-CH 3 ) to be (1.7 Ϯ 0.4) ϫ 10 Ϫ12 cm 3 molecule Ϫ1 s Ϫ1 at 297 Ϯ 3 K and 1 atmosphere total pressure. To more clearly define MIB's