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Rate constants of reactions of κ-carrageenan with hydrated electron and hydroxyl radical

✍ Scribed by L.V. Abad; S. Saiki; H. Kudo; Y. Muroya; Y. Katsumura; A.M. de la Rosa


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
496 KB
Volume
265
Category
Article
ISSN
0168-583X

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✦ Synopsis


The rate constants for the reactions of j-carrageenan with hydrated electron and hydroxyl radical was investigated by pulse radiolysis and laser photolysis. The kinetics of the reaction of hydrated electron indicates no seeming reaction with j-carrageenan. On the other hand, hydroxyl radical reacts very rapidly with j-carrageenan at a rate constant of approximately 1.2 • 10 9 M À1 s À1 . This rate constant varies with pH.


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