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Tables of bimolecular rate constants of hydrated electrons, hydrogen atoms and hydroxyl radicals with inorganic and organic compounds

✍ Scribed by M. Anbar; P. Neta


Publisher
Elsevier Science
Year
1965
Weight
903 KB
Volume
16
Category
Article
ISSN
0020-708X

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## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^

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## Abstract Rate constants for the gas‐phase reactions of hydroxyl radicals and chlorine atoms with a series of alcohols have been determined by using the relative method. The experiments were performed at 295 ± 2 K and at 1 atmospheric pressure. The obtained values of the rate constants in units o

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Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, COa'-, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80°C. The reactants include the substitution-inert cyano complexes of Fe", Mo", and W"

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## Abstract Rate constants for the gas‐phase reactions of hydroxyl radicals and chlorine atoms with aliphatic alcohols and ethers have been determined at 298 ± 2 K and at a total pressure of 1 atmosphere. The OH radical rate data were obtained using both the absolute technique of pulse radiolysis c