Reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in micellar systems
✍ Scribed by Krishan M. Bansal; L.K. Patterson; E.J. Fendler; J.H. Fendler
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 809 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-7055
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## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^
By photolyzing (CF,H),CO and (CFH,),CO the hydrogen atom abstraction reactions of CF,H radicals with (CF,H),CO, H, , D, , CH, , C,H, , n-C,H,, and iso-C,H1,, and the reactions of CFH, radicals with (CFH,),CO and n-C,H,, , have been studied. Arrhenius parameters for these reactions are compared with