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Rate constants for the reactions of N(2D) atoms with O2, H2 and HF

✍ Scribed by Philip D. Whitefield; Floyd E. Hovis

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 559 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85189-8

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✦ Synopsis

The rate constants k,, k2 and t for the reactions of N( 'D) atoms with I-I>, HF, and 02, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 kO.8) x IO-'*, (1.0_+0.3) x lo-'" and (6.6 f 1.0) X lo-l2 cm3 s-l, respectively. Previously published data on k, and k3 exist and there is good agreement between those studies and that described herein.

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