The CHsOs radical was generated by pulsed laser photolysis and was detected directly by photoionization mass spectrometry. The radical was photoionized by the Ar resonance lines ( 11.62 and 11.83 eV) and detected as the parent ion, CHsO: . Reactions of CH302 and CDs02 with NO were studied by time-re
Rate constant measurement for the reaction of D3+ with H2
โ Scribed by David L. Smith; Jean H. Futrell
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 385 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The rate c&Want and the product distriblition for the reaction of D; w&h I& has been masured as a function of the Dz vibrational energy. in these experiments a mass analyzed bfzam of D3 ions is de&crated to le& than 0.1 eV and is subsequently injected into an ion cyclotron resonance (ICR) cell where reaction with Hz may occur. Ion detection is achi&ed usinc: a conventional oscillatordetector. The number of Dz-D2 coliisions was varied from 0 to 10 by changing ffie D5 pressurein the SGLUCX of the fust stage of the instrur~ent.
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