The rate constant for the reaction NHa + OH + NH= + Hz0 was determined by the comparison of the calculated induo tion period data with experiments by the shock tube technique in the range 1360-1840 K, for NHs-Ha-02-\_Ar mixtures\_ The rate constants can be represented by the expression k = 1012-4g'o
A priori rate constant for the reaction NH2+NO → N2+H2O
✍ Scribed by L.F. Phillips
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 542 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0009-2614
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The rate constant for the reaction BrO + NO -+ Br f NO2 has been determine4 over the tempemture range 230 I( to 425 K in a discharge flow system using a mass spectrometer as a detector\_ Results, expressed in the Arrhenius form kr = (7.11 5 0.23) X 10-t\* eup[(296 f 10)/T] cm3 s-t, are compared with
The reaction involves two short-lived collision complexes, BHNOf and HBONt, which rearrange to products BO+NH via the same cyclic transition state. The overall rate constant depends on the rates of complex formation by capture over the centrifugal barrier in the dipole-dipole potential, and the rate