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Rate constant for the reaction NH3 + OH → NH2 + H2O over a wide temperature range

✍ Scribed by Joel A. Silver; Charles E. Kolb

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
321 KB
Volume
75
Category
Article
ISSN
0009-2614

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Determination of the rate constant for t
Determination of the rate constant for the reaction NH3 + OH → NH2 + H2O
✍ N. Fujii; H. Miyama; T. Asaba 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 233 KB

The rate constant for the reaction NHa + OH + NH= + Hz0 was determined by the comparison of the calculated induo tion period data with experiments by the shock tube technique in the range 1360-1840 K, for NHs-Ha-02-\_Ar mixtures\_ The rate constants can be represented by the expression k = 1012-4g'o

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Kinetics of the reactions OH (v = O) + NH3 →; H2O + NH2 and OH(v = O) + O3 → HO2 + O2 AT 298°K
✍ Michael J. Kurylo 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 400 KB

The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u

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✍ A. Grant Thaxton; C.-C. Hsu; M. C. Lin 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB 👁 2 views

The rate constant for the NH 3 ϩ NO 2 L NH 2 ϩ HONO reaction (1) has been kinetically modeled by using the photometrically measured NO 2 decay rates available in the literature. The rates of NO 2 decay were found to be strongly dependent on reaction (1) and, to a significant extent, on the secondary