By using relative rate methods, rate constants for the gas-phase reactions of OH and NO 3 radicals with propanal, butanal, pentanal, and hexanal have been measured at 296 ฯฎ 2 K and atmospheric pressure of air. By using methyl vinyl ketone as the reference compound, the rate constants obtained for th
Rate constants for the gas-phase reactions of OH radicals with a series of unsaturated alcohols
โ Scribed by Christine Papagni; Janet Arey; Roger Atkinson
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 90 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0538-8066
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๐ SIMILAR VOLUMES
Using a relative rate method, rate constants have been measured for the gasphase reactions of the OH radical with the dibasic esters dimethyl succinate The rate constants ob-298 ฯฎ 3 K. tained were (in units of ): dimethyl succinate, dimethyl 10 cm molecule s 1.4 ฯฎ 0.6; glutarate, and dimethyl adip
The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f
dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac
Absolute rate constants for the reactions of OH radicals with butyl ethyl ether ( k , ) , methyl tertbutyl ether (k2), ethyl tert-butyl ether ( k ] ) , tert-amyl methyl ether ( k 4 ) ) , and tert-butyl alcohol ( k 5 ) have been measured over the temperature range 230-372 K using a pulsed laser photo
The pulsed laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ketones, at room temperature (298 ฯฎ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule ฯช1