Rate Constants and Arrhenius Parameters for the Reaction of Acyl Radicals with Bu3SnH and (Me3Si)3SiH
β Scribed by Chatgilialoglu, C.; Ferreri, C.; Lucarini, M.; Pedrielli, P.; Pedulli, G. F.
- Book ID
- 127127471
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 606 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
The angular and velocity distribution of the ICl product from reaction (1) at 4.5 kcal/mol collision energy has been obtained by Cross and Blais in a crossed-molecular-beam study [1]. It was concluded that the angular distribution is consistent with that arising from short range attractive forces an
The rate constant of the reaction, OH + NH3 -+ Hz0 + NH2, has been measured at temperatures between 230 and 490'K using time-resolved resonance absorption to observe the concemytion of OH radicals..An Arrhenius expression, kI = 2.3 X lO\_" exp(-1.6 kcai mole-'/RT) cm3 molecule-' set , was obtained.