Rate constants for the reaction of acyl radicals with Bu3SnH and (TMS)3SiH
β Scribed by Chryssostomos Chatgilialoglu; Marco Lucarini
- Book ID
- 103402167
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 199 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
The angular and velocity distribution of the ICl product from reaction (1) at 4.5 kcal/mol collision energy has been obtained by Cross and Blais in a crossed-molecular-beam study [1]. It was concluded that the angular distribution is consistent with that arising from short range attractive forces an
The gas-phase reaction of NO 3 radicals with selected oxiranes has been studied in a flow system at T = 295 + 2 K in the pressure range 3.4-50 mbar using N 2 as carrier gas. The analysis of the organics was performed by means of on-line connected GC-FID. Rate constants were obtained with the relativ