✦ LIBER ✦

Rate constants for the reactions of OH with NH3 and HNO3

✍ Scribed by Reinhard Zellner; Ian W.M. Smith

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 273 KB
Volume: 26
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)89086-x

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✦ Synopsis

The rate constant of the reaction, OH + NH3 -+ Hz0 + NH2, has been measured at temperatures between 230 and 490'K using time-resolved resonance absorption to observe the concemytion of OH radicals..An Arrhenius expression, kI = 2.3 X lO_" exp(-1.6 kcai mole-'/RT) cm3 molecule-' set , was obtained. Similar experiments, between 240 and 405°K. have teen carried out on OH + HNO 3 -, Hz0 + N03, and k3 = (0.9 -+ 0.2) x IO-l3 cm3 molecule-' set+ throughout this range of temperature.

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