Rate constants and Arrhenius functions for rearrangements of the 2,2-dimethyl-3-butenyl and (2,2-dimethylcyclopropyl)methyl radicals
β Scribed by Newcomb, Martin; Glenn, Anne G.; Williams, William G.
- Book ID
- 126295145
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 907 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
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Rate constants for the reaction of CN( u= 0) with Cl,, FZ and O2 have been measured. CN radicals were generated by photolysis of C2Nz with pulsed radiation at 193 nm. Laser-induced fluorescence (LIF) was used to monitor the decay profiles of CN radical concentrations. The valuesobtainedare: k(CN/CI?
## Abstract The kinetics of the reactions of ground state oxygen atoms with __trans__β2βbutene, __cis__β2βbutene, 2βmethylpropene, 2βmethylβ2βbutene, and 2,3βdimethylβ2βbutene was investigated in the temperature range 200 to 370K. In this range, the rate constants are (in units 10^β11^ cm^3^ s^β1^)
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