Rate constants and arrhenius function for scavenging of octyl radical by an N-hydroxypyridine-2-thione ester

✍ Scribed by Martin Newcomb; Jere Kaplan

• Book ID: 104227140
• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 256 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)95373-5

✦ Synopsis

Rate constants for reactions of octyl radical with its N-hydroxypyridine-2-thione ester precursor were determined using the reduction of octyl radical by n-Bu SnH as a competition reaction.

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The use of radical cyclization and functionalization steps in organic synthesis is becoming increasingly popular.