Rate Constant Rules for the Automated Generation of Gas-Phase Reaction Mechanisms †
✍ Scribed by Carstensen, Hans-Heinrich; Dean, Anthony M.
- Book ID
- 126790924
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 778 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction rates of SO3 with CH,OH in He were measured at total pressures of 0.7-1.6 torr in flow tubes. The concentration of SO3 was monitored by the SOz\* fluorescence from excitation of SO3 at 147 nm. The reaction rate constant of SO3 + CH30H in the gas phase is determined to be (1.17 ? 0.16) x
The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ϭ 1 constants, in units of cm 3 molecule Ϫ1 s Ϫ1 , are for 2 (5H)-furanone, Ϫ18 10 0.22 Ϯ 0.05 for methacrolein, for crotonaldehyde, f
## By observing mass spectrometrically the decay of H# in flames the ratio of the rate constants for the neutmfization of H30t by Cl-and the electron has been measured as 0.11 f 0.03 over the temperature range 1800-2600°K.
## Receiwd 16 Ma> 1979 MoIecuhr modulation spectrometry has been employed to mesure the rate constants for the reactions ofCHxO2 with HOz. NO2 and X0. A negnthe tcmpcraturc dependence is reported for the rextion nirh HO\_r. Product spectra are giwn for the reactions with lIOt and NO?\_