## Abstract The reaction mechanism of CF~3~CH~2~OH with OH is investigated theoretically and the rate constants are calculated by direct dynamics method. The potential energy surface (PES) information, which is necessary for dynamics calculation, is obtained at the B3LYP/6โ311G (d, p) level. The si
Reaction rate constant of SO3 + CH3OH in the gas phase
โ Scribed by Guanlin Shen; Masako Suto; L. C. Lee
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 375 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
The reaction rates of SO3 with CH,OH in He were measured at total pressures of 0.7-1.6 torr in flow tubes. The concentration of SO3 was monitored by the SOz* fluorescence from excitation of SO3 at 147 nm. The reaction rate constant of SO3 + CH30H in the gas phase is determined to be (1.17 ? 0.16) x cm3 m o l e c -' ~-~ a t room temperature.
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