✦ LIBER ✦

Rate constant for the reaction of OH with nitric acid: A new investigation by discharge flow resonance fluorescence

✍ Scribed by P. Devolder; M. Carlier; J.F. Pauwels; L.R. Sochet

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 588 KB
Volume: 111
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80443-1

No coin nor oath required. For personal study only.

✦ Synopsis

The absolute rate constant of the title reaction has been measured using the technique of discharge flow resonance fiuorcscencc over the temperature range X3-373 K. An Arrhcnius plot of the data below room temperature can be fittedbp a nc_Wive activation energy E/R = -S43 K. The room-temperature value of the rate constant kt = (0.93 f 0.10) x lo-l3 cm3 molecule-' s-' . . 1s m excellent agreement with previous discharge flow studies using optical dctcction but lies significantly below the results from flash photolysis investigations. V01ume 111, number 1.2 CHEhlICAL PHYSiCS LJZI-X-ERS 2.

📜 SIMILAR VOLUMES

Determination of the rate constant of re

Determination of the rate constant of reaction of ground-state CI and H atoms with H2S using resonance fluorescence in a discharge flow

✍ Michael A.A. Clyne; Yoko Ono 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 538 KB

Absolute rate constants of the reactions

Absolute rate constants of the reactions of OH with cyclohexane and ethane at 296 ± 2 K by the discharge flow method

✍ Nourredine Bourmada; Christian Lafage; Pascal Devolder 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 535 KB

We present absolute measurements of the rate constant for the reactions of OH with cyclohexane: k, = (8.6 rtO.8) x lo-" cm3 molecule-' s-l and with ethane: k3= (2.74f0.3) x lo-l3 cm3 molecule-\* s-l, both measured at room temperature by discharge flow resonance fluorescence. Our result fork, is abov

A reinvestigation of the temperature dep

A reinvestigation of the temperature dependence of the rate constant for the reaction O + O2 + M → O3 + M (for M = O2, N2, and Ar) by the flash photolysis resonance fluorescence technique

✍ Odo Klais; Philip C. Anderson; Michael J. Kurylo 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 915 KB

## Abstract The flash photolysis resonance fluorescence technique has been used to reinvestigate the kinetics of the oxygen atom–oxygen molecule combination reaction. Third‐order rate constants for O~2~, N~2~, and Ar as deactivant molecules were determined over the temperature range of 219–368 K. T