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A reinvestigation of the temperature dependence of the rate constant for the reaction O + O2 + M → O3 + M (for M = O2, N2, and Ar) by the flash photolysis resonance fluorescence technique

✍ Scribed by Odo Klais; Philip C. Anderson; Michael J. Kurylo

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
915 KB
Volume
12
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The flash photolysis resonance fluorescence technique has been used to reinvestigate the kinetics of the oxygen atom–oxygen molecule combination reaction. Third‐order rate constants for O~2~, N~2~, and Ar as deactivant molecules were determined over the temperature range of 219–368 K. The results presented herein are the most extensive data sets available for atmospheric modeling and are used to formulate a recommendation for such purposes. The recommended rate expressions are
or
Comparisons of these results with existing literature data are presented.

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