Absolute rate constants for the reaction of S(3P) with ethylene were measured over an ethylene concentration range of 7, a total pressure of 50 to 400 tom, and a flash intensity range of 10. At 298"K, the bimolecular rate constant was found to be invariant over this range of variables a& had a measu
Determination of the rate constant of reaction of ground-state CI and H atoms with H2S using resonance fluorescence in a discharge flow
✍ Scribed by Michael A.A. Clyne; Yoko Ono
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 538 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0009-2614
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The absolute rate constant of the title reaction has been measured using the technique of discharge flow resonance fiuorcscencc over the temperature range X3-373 K. An Arrhcnius plot of the data below room temperature can be fittedbp a nc\_Wive activation energy E/R = -S43 K. The room-temperature va
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