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Absolute rate constants of the reactions of OH with cyclohexane and ethane at 296 ± 2 K by the discharge flow method

✍ Scribed by Nourredine Bourmada; Christian Lafage; Pascal Devolder

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
535 KB
Volume
136
Category
Article
ISSN
0009-2614

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✦ Synopsis

We present absolute measurements of the rate constant for the reactions of OH with cyclohexane: k, = (8.6 rtO.8) x lo-" cm3 molecule-' s-l and with ethane: k3= (2.74f0.3) x lo-l3 cm3 molecule-* s-l, both measured at room temperature by discharge flow resonance fluorescence. Our result fork, is above the average of two previously published measurements, but is in agreement with the preferred values of two recent reviews, as deduced from either relative measurements or theoretical correlations.

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