Relative rate constants for the gas-phase reactions of C1-atom with thirteen atmospherically interesting alkanes ( c 2 -C ~) have been determined at 296 i-2 K based on GC/FID measurements of their relative decays in the UV (A 2 300 nm) photolysis of mixtures containing Cl2 and the entire series of t
Rate constants for the gas-phase reactions of alkanes with Cl atoms at 296 ± 2 K
✍ Scribed by Sara M. Aschmann; Roger Atkinson
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 538 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Rate constants for the gas-phase reactions of the C1 atom with a series of alkanes have been determined at 296 t 2 K using a relative rate method. Using a rate constant for the C1 atom reaction with n-butane of 1.94 x cm3 molecule-I s-l, the rate constants obtained (in units of 10-l' cm3 molecule-l s-l)
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