Radical chlorination of tetracyclo[3.3.0.02,7.04,6]octane and tetracyclo[3.3.0.02,4.03,7]octane with tert-butyl hypochlorite
β Scribed by Freeman, Peter K.; Ziebarth, Timothy D.
- Book ID
- 127022648
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 567 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Cyclooctatetraene is a common product of photolysis of the title compound la. Depending on reaction conditions it is accompanied by benzene (solvent: cyclohexane, Ξ³ = 253.7 nm), benzene plus semibullvalene (acetone, 300 nm), and an oxetane (cyclohexane, 350 nm, presence of an equimolar
Das energiereiche tetracyclische Geriist 1photochemisch leicht zugiinglich -hat iiber thermische und katalysierte Prozesse Zugang zu einer GroRzahl h&fig anderweitig kaum zuganglicher Derivate der Valenzisomeren 2-4 1) --eriiffnet. AnlaO dieser hlitteilung
The synthesis of the hydrocarbons 4-5 has been achieved via Wittig reaction from the diketones J-2. By means of He(I)photoelect spectroscopy it is shown that the interaction between the r-fragments in 2-g increases strongly. Recently we demonstrated by means of He(I)photoelect (PE) spectroscopy