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Through bond and through space interaction in 1,5-dimethyl-3,7-dimethylene-tetracyclo[3.3.0.02,8.04,6]octane

✍ Scribed by Rolf Gleiter; Gerhard Jähne

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
185 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of the hydrocarbons 4-5 has been achieved via Wittig reaction from the diketones J-2. By means of He(I)photoelect spectroscopy it is shown that the interaction between the r-fragments in 2-g increases strongly.

Recently we demonstrated by means of He(I)photoelect (PE) spectroscopy

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✍ Mangalam S Nair; Uma Sudhir; S Joly; Nigam P Rath 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 426 KB

A novel entry into 3-bromo-7-(bromomethyt)tetracyclo[5.3.1.02"6.04"S]undec~10(12)-ene-9,11-dione, which readily undergoes further rearrangement with primary amines, has been developed through photolysis of 2,5bis(bromomethyl)tricyelo[6.2.1.02"7]undec-4,9-diene-3,6-dione.