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Synthesis and solvolytic studies of tetracyclo[4.2.0.02,5.04,7]octan-3-yl (secocubane) derivatives

โœ Scribed by Dauben, William G.; Reitman, Larry N.


Book ID
126469288
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
918 KB
Volume
40
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Solvolytic studies of stereoisomeric tri
โœ Leo A. Paquette; O. Cox; M. Oku; R.P. Henzel; J.A. Schwartz ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 245 KB

The accelerated solvolytic behavior of exo-and endo-bicyclo[3.l.O]alk-2-yl derivatives provides convincing evidence that comparable cyclopropyl participation accompanies ionization of both epimers. 2 The pair of isomers react at very similar rates (k,ndo/k+xo = 1.3-l.5 depending on the leaving group